| Season | Player | Team(s) | Goals Scored |
| 1928/1929 | Paco Bienzobas | Real Sociedad | 17 |
| 1929/1930 | Guillermo Gorostiza | Athletic Bilbao | 20 |
| 1930/1931 | Bata | Athletic Bilbao | 27 |
| 1931/1932 | Bata | Athletic Bilbao | 13 |
| 1932/1933 | Manuel Olivares | Real Madrid | 16 |
| 1933/1934 | Isidro Lángara | Real Oviedo | 26 |
| 1934/1935 | Isidro Lángara | Real Oviedo | 27 |
| 1935/1936 | Isidro Lángara | Real Oviedo | 28 |
| 1939/1940 | Victor Unamuno | Athletic Bilbao | 20 |
| 1940/1941 | Pruden | Atletico Madrid | 33 |
| 1941/1942 | Edmundo Suárez de Trabanco | Valencia CF | 27 |
| 1942/1943 | Mariano Martín Alonso | FC Barcelona | 30 |
| 1943/1944 | Edmundo Suárez de Trabanco | Valencia CF | 28 |
| 1944/1945 | Telmo Zarra | Athletic Bilbao | 20 |
| 1945/1946 | Telmo Zarra | Athletic Bilbao | 24 |
| 1946/1947 | Telmo Zarra | Athletic Bilbao | 33 |
| 1947/1948 | Pahiño | Celta de Vigo | 20 |
| 1947/1948 | Francisco Peralta | Gimnàstic de Tarragona | 20 |
| 1948/1949 | César Rodríguez Álvarez | FC Barcelona | 28 |
| 1949/1950 | Telmo Zarra | Athletic Bilbao | 24 |
| Season | Player | Team(s) | Goals Scored |
| 1950/1951 | Telmo Zarra | Athletic Bilbao | 38 |
| 1951/1952 | Pahiño | Real Madrid | 28 |
| 1952/1953 | Telmo Zarra | Athletic Bilbao | 24 |
| 1953/1954 | Alfrédo di Stefano | Real Madrid | 27 |
| 1954/1955 | Juan Arza | Sevilla FC | 29 |
| 1955/1956 | Alfrédo di Stefano | Real Madrid | 24 |
| 1955/1956 | Mauro Rodriguez | Celta de Vigo | 24 |
| 1956/1957 | Alfrédo di Stefano | Real Madrid | 31 |
| 1957/1958 | Alfrédo di Stefano | Real Madrid | 19 |
| 1957/1958 | Ricardo Alós | Valencia CF | 19 |
| 1957/1958 | Manuel Badenes | Real Valladolid | 19 |
| 1958/1959 | Alfrédo di Stefano | Real Madrid | 23 |
| 1959/1960 | Ferenc Puskas | Real Madrid | 25 |
| 1960/1961 | Ferenc Puskas | Real Madrid | 28 |
| 1961/1962 | Juan Seminario | Real Zaragoza | 25 |
| 1962/1963 | Ferenc Puskas | Real Madrid | 26 |
| 1963/1964 | Ferenc Puskas | Real Madrid | 21 |
| 1964/1965 | Cayetano Ré | FC Barcelona | 26 |
| 1965/1966 | Luis Aragonés | Atletico Madrid | 19 |
| 1965/1966 | Luciano Sánchez | Elche CF | 19 |
| Season | Player | Team(s) | Goals Scored |
| 1966/1967 | Waldo | Valencia CF | 24 |
| 1967/1968 | Fidel Uriarte | Athletic Bilbao | 22 |
| 1968/1969 | Amaro Amancio | Real Madrid | 14 |
| 1968/1969 | José Gárate | Atletico Madrid | 14 |
| 1969/1970 | Luis Aragonés | Atletico Madrid | 16 |
| 1969/1970 | Amaro Amancio | Real Madrid | 16 |
| 1969/1970 | José Gárate | Atletico Madrid | 16 |
| 1970/1971 | Carles Rexach | FC Barcelona | 17 |
| 1970/1971 | José Gárate | Atletico Madrid | 17 |
| 1971/1972 | Enrique Porta | Granada CF | 20 |
| 1972/1973 | Marianin | Real Oviedo | 19 |
| 1973/1974 | Quini | Sporting Gijón | 20 |
| 1974/1975 | Carlos Ruiz | Athletic Bilbao | 19 |
| 1975/1976 | Quini | Sporting Gijón | 21 |
| 1976/1977 | Mario Kempes | Valencia CF | 24 |
| 1977/1978 | Mario Kempes | Valencia CF | 28 |
| 1978/1979 | Hans Krankl | FC Barcelona | 29 |
| 1979/1980 | Quini | Sporting Gijón | 24 |
| 1980/1981 | Quini | FC Barcelona | 20 |
| Season | Player | Team(s) | Goals Scored |
| 1981/1982 | Quini | FC Barcelona | 27 |
| 1982/1983 | Hipólito Rincón | Real Betis | 20 |
| 1983/1984 | Juanito | Real Madrid | 17 |
| 1983/1984 | Jorge Da Silva | Real Valladolid | 17 |
| 1984/1985 | Hugo Sánchez | Atletico Madrid | 19 |
| 1985/1986 | Hugo Sánchez | Real Madrid | 22 |
| 1986/1987 | Hugo Sánchez | Real Madrid | 34 |
| 1987/1988 | Hugo Sánchez | Real Madrid | 29 |
| 1988/1989 | Baltazar | Atletico Madrid | 35 |
| 1989/1990 | Hugo Sánchez | Real Madrid | 38 |
| 1990/1991 | Emilio Butragueño | Real Madrid | 19 |
| 1991/1992 | Manolo | Atletico Madrid | 27 |
| 1992/1993 | Bebeto | Deportivo La Coruña | 29 |
| 1993/1994 | Romário | FC Barcelona | 30 |
| 1994/1995 | Ivan Zamorano | Real Madrid | 28 |
| 1995/1996 | Juan Antonio Pizzi | CD Tenerife | 31 |
| 1996/1997 | Ronaldo | FC Barcelona | 34 |
| 1997/1998 | Christian Vieri | Atletico Madrid | 24 |
| 1998/1999 | Raúl | Real Madrid | 25 |
| 1999/2000 | Salva Ballesta | Racing Santander | 27 |
| Season | Player | Team(s) | Goals Scored |
| 2000/2001 | Raúl | Real Madrid | 24 |
| 2001/2002 | Diego Tristán | Deportivo La Coruña | 20 |
| 2002/2003 | Roy Makaay | Deportivo La Coruña | 29 |
| 2003/2004 | Ronaldo | Real Madrid | 24 |
| 2004/2005 | Diego Forlán | Villareal CF | 25 |
| 2005/2006 | Samuel Eto’o | FC Barcelona | 27 |
| 2006/2007 | Ruud van Nistelrooy | Real Madrid | 25 |
| 2007/2008 | Dani Güiza | RCD Mallorca | 27 |
| 2008/2009 | Diego Forlán | Atletico Madrid | 27 |
| 2009/2010 | Lionel Messi | FC Barcelona | 34 |
| 2010/2011 | Cristiano Ronaldo | Real Madrid | 41 |
| 2011/2012 | Lionel Messi | FC Barcelona | 50 |
| 2012/2013 | Lionel Messi | FC Barcelona | 46 |
| 2013/2014 | Cristiano Ronaldo | Real Madrid | 31 |
| 2014/2015 | Cristiano Ronaldo | Real Madrid | 48 |
| 2015/2016 | Luis Suárez | FC Barcelona | 40 |
| 2016/2017 | Lionel Messi | FC Barcelona | 37 |
| 2017/2018 | Lionel Messi | FC Barcelona | 34 |
| 2018/2019 | Lionel Messi | FC Barcelona | 36 |
| 2019/2020 | Lionel Messi | FC Barcelona | 25 |
| 2020/2021 | Lionel Messi | FC Barcelona | 25 |
| 2021/2022 | Karim Benzema | Real Madrid | 27 |